Usually if you get smoke just at start up it's the valve seals, if it's on overrun then it's guides and if it's on acceleration it's rings or bore wear. Well that's what I've found.
I am no expert but from my experience valve stem seals perishing have no noticeable effect on engine performance. Good indicator would be to leave the car idling for a few minutes and then check if the bit of smoke you noticed becomes significantly larger.